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5.35 Introduction to Experimental Chemistry (MIT) 5.35 Introduction to Experimental Chemistry (MIT)

Description

This course is the first part of a modular sequence of increasingly sophisticated (and challenging) laboratory courses required of all Chemistry majors: 5.35 Introduction to Experimental Chemistry, 5.36 Biochemistry and Organic Laboratory, 5.37 Organic and Inorganic Laboratory, and 5.38 Physical Chemistry Laboratory. This course provides students with a survey of spectroscopy, and introduces synthesis of coordination compounds and kinetics. This class is part of the new laboratory curriculum in the MIT Department of Chemistry. Undergraduate Research-Inspired Experimental Chemistry Alternatives (URIECA) introduces students to cutting edge research topics in a modular format.   AcknowledgementsProfessor Nelson and Dr. Twardowski would like to acknowledge the contribution This course is the first part of a modular sequence of increasingly sophisticated (and challenging) laboratory courses required of all Chemistry majors: 5.35 Introduction to Experimental Chemistry, 5.36 Biochemistry and Organic Laboratory, 5.37 Organic and Inorganic Laboratory, and 5.38 Physical Chemistry Laboratory. This course provides students with a survey of spectroscopy, and introduces synthesis of coordination compounds and kinetics. This class is part of the new laboratory curriculum in the MIT Department of Chemistry. Undergraduate Research-Inspired Experimental Chemistry Alternatives (URIECA) introduces students to cutting edge research topics in a modular format.   AcknowledgementsProfessor Nelson and Dr. Twardowski would like to acknowledge the contribution

Subjects

Chemistry | Chemistry | experimental chemistry | experimental chemistry | spectroscopy | spectroscopy | synthesis of coordination compounds and kinetics | synthesis of coordination compounds and kinetics | IR Spectroscopy | IR Spectroscopy | IR Spectroscopy of Proteins | IR Spectroscopy of Proteins | 15 MHz NMR | 15 MHz NMR | 300 MHz | 300 MHz | Lambert-Beer | Lambert-Beer | Kinetics Measurements | Kinetics Measurements

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Content within individual OCW courses is (c) by the individual authors unless otherwise noted. MIT OpenCourseWare materials are licensed by the Massachusetts Institute of Technology under a Creative Commons License (Attribution-NonCommercial-ShareAlike). For further information see http://ocw.mit.edu/terms/index.htm

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Chemistry 107. Inorganic Chemistry. Lecture 18.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 18. Inorganic Chemistry -- Chemistry of the Main Group Elements -- Boron through Nitrogen Groups View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 14, 2014. Index of Topics: 00:16-Chemistry of the Main Group Elements: Boron through Nitrogen Groups 00:58-Solvated Electron Solutions 04:29-Alkalides and Electrides 10:17-Organometallic Chemistry 13:14-More Organolithium Chemistry 15:57-Organomagnesium Chemistry 19:15-Organomagnesium Reactivity 20:43-Group IIIA: B, Al, Ga, In, and Tl 30:31-Boron Hydride Clusters 39:07-Carbon 45:25-Si, Ge, Sn, & Pb Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 22.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 22. Inorganic Chemistry -- Coordination Chemistry I: Coordination Geometries View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 24, 2014. Index of Topics: 00:07 - Coordination Chemistry I: Coordination Geometries 01:21 - Coordination Geometries 04:02 - Coordination Number 1 06:30 - Coordination Number 2 10:27 - Coordination Number 3 15:06 - Coordination Number 4 18:21 - Coordination Number 5 24:41 - Coordination Number 6 30:52 - Coordination Number 7 34:50 - Coordination Number 8 and Higher 38:27 - Coordination Chemistry II: Theories of Electronic Structure 38:39 - Experimental Evidence for Electronic Structure 44:47 - Theories of Electronic Structures Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 20.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 20. Inorganic Chemistry -- Chemistry of the Main Group Elements -- Chalcogens through Noble Gases View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 19, 2014. Index of Topics: 00:24-Sulfur 03:10-Sulfur Halides 06:56-Halogens 12:41-Interhalogens 16:48-Halogen Oxo-Anions 20:40-Noble Gases 23:27-Coordination Chemistry 1: Structures and Isomers 24:44-Coordination Chemistry 32:49-Formulae & Nomenclature Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 23.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 23. Inorganic Chemistry -- Coordination Chemistry II: Liquid Field Theory View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 26, 2014. Index of Topics: 00:17 - Coordination Chemistry II: Ligand Field Theory 02:09 - Theories of Electronic Structures 03:35 - Valence Bond Theory 08:16 - Crystal Field Theory 15:26 - Calculating the CFSE 18:22 - Ligand Field Theory 23:13 - Symmetry 27:59 - ML6 Octahedral MO Diagram 34:26 - MO Pictures 41:05 - Adding Metal Electrons Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 25.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 25. Inorganic Chemistry -- Coordination Chemistry II: LFT for Electron Counting View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on December 3, 2014. Index of Topics: 00:17 - Coordination Chemistry II: LFT for Td and D3h Complexes & Electron Counting 03:39 - Angular Overlap Method 05:34 - ML6 Octahedral MO Diagram 06:54 - Using the AOM 09:10 - Tetrahedral Complexes 12:51 - ML4 Tetrahedral MO Diagram 16:16 - T2 Hybridization of Metal Complexes 21:28 - ML4 Tetrahedral MO Diagram 25:12 - Tetrahedral Coordination Complexes 28:20 - Trigonal Bipyramidal Complexes 33:52 - ML5 TBP MO Diagram 38:33 - TBP Coordination Complexes 42:16 - 18 Electron Rule Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 26.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 26. Inorganic Chemistry -- Coordination Chemistry III: Spectroscopy & Multi-Electron States View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on December 5, 2014. Index of Topics: 00:17 - Coordination Chemistry III: Spectroscopy & Multi-Electron States 01:06 - Intro to Spectroscopy 05:42 - "Rules" for Spectroscopy 11:59 - [Ti(OH2)6]3+ 17:53 - [V(OH2)6]3+ 21:58 - Crystal Field Theory 23:11 - Tackling the Multi-Electron Problem 27:50 - Multi-Electron Quantum Numbers 31:39 - The V3+ Free Ion 35:24 - V3+ Microstate Table Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 28.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 28. Inorganic Chemistry -- Coordination Chemistry III: Multi-Electron States -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on December 10, 2014. Index of Topics: 00:17 - Coordination Chemistry III: Multi-Electron States 01:51 - Understanding the [V(OH2)6]3+ Spectrum 07:13 - Visualizing the 3F and 3P States 10:26 - Electronic State Diagram 21:25 - d2 Tanabe Sugano Diagram 30:25 - d7 Tanabe Sugano Diagram 44:29 - Sample Problem, [Co(NH3)6]2+ 50:59 - Jahn-Teller Effect Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 15

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 15. Inorganic Chemistry -- Models of Acid- Base Chemistry View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Matthew D. Law License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Matthew D. Law. Recorded on November 5, 2014. Index of Topics: 00:17-Models of Acid-Base Chemistry 04:12-Arrhenius Acid-Base Model 05:49-Bronsted-Lowry Model 08:40-Solvent System Model 12:34-The Lewis Concept 16:40-The Lewis Concept and Molecular Orbitals 31:36-HSAB Model 37:00-HSAB Theory 39:44-HSAB Theory and Exchange Reactions 41:19-HSAB Theory and Solubilities 44:00-HSAB Theory and Metal Thiocyanate Complexes 46:42-Pearson's Absolute Hardness Scale 49:50-The Nature of the Adduct Required attribution: Law, Matthew D. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 17

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 17. Inorganic Chemistry -- Chemistry of the Main Group Elements -- Hydrogen, Alkali, and Alkaline Earth Metals View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 12, 2014. Index of Topics: 00:17-Solvation Effects 07:06-Leveling Effects 12:23-Chemistry of the Main Group Elements: Hydrogen, Alkali and Alkaline Earth Metals 14:25-Hydrogen 18:02-Hydrogen Production 21:21-Hydrogen Use 24:15-The Hydrogen Economy 27:10-Types of Hydrogen Compounds 31:10-Hydride Stability 35:43-Hydride Synthesis and Reactivity 40:16-Alkali & Alkaline Earth Metals Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 19.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 19. Inorganic Chemistry -- Chemistry of the Main Group Elements -- Carbon Group through Noble Gases View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 17, 2014. Topic of Index: 00:17-Chemistry of the Main Group Elements: Carbon Group Through Nobel Gases 00:47-Si, Ge, Sn, & Pb 02:22-Group IVA Geometries 04:30-Multiple Bonding 10:45-Nitrogen 12:49-NOx: N^v 15:13-NOx: N^II and N^IV 18:45-NOx: NO 22:11-Low-Valent Nitrogen Compounds 27:23-P, As, Ab, & Bi 32:39-Oxygen 45:21-Oxides Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 21.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 21. Inorganic Chemistry -- Coordination Chemistry I: Names, Coordination Geometries and Isomers View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on November 21, 2014. Index of Topics: 00:18 - Coordination Chemistry 1: Names, Coordination Geometries and Isomers 00:36 - Formulae & Nomenclature 16:18 - Multidentate Ligands 21:00 - Isomerism 22:38 - Constitutional Isomers 33:18 - Configurational Isomers 35:39 - Chirality 41:27 - Chelate Ring Conformations 44:36 - Ligand Ring Conformations 47:04 - Coordination Geometries Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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General Chemistry 1A. Lecture 01. Introduction to General Chemistry.

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UCI Chem 1A General Chemistry (Winter 2013) Lec 01. General Chemistry Introduction to General Chemistry View the complete course: http://ocw.uci.edu/courses/chem_1a_general_chemistry.html Instructor: Amanda Brindley, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Chem 1A is the first quarter of General Chemistry and covers the following topics: atomic structure; general properties of the elements; covalent, ionic, and metallic bonding; intermolecular forces; mass relationships. General Chemistry (Chem 1A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 23-lecture undergraduate-level course titled "General Chemistry" taught at UC Irvine by Amanda Brindley, Ph.D. Recorded February 25, 2013. Index of Topics: 0:01:55 "Fundamentals" 0:02:40 Significant Figures 0:11:44 Dimensional Analysis: Conversion Factors 0:12:30 Fundamental Problems 0:22:22 Structure of an Atom 0:25:07 Cartoon 0:26:06 Isotopes, Natural abundance, and Molecular Mass 0:29:11 Average Molecular Mass 0:32:29 Periodic Table 0:34:21 Naming 0:37:12 Bonding 0:38:09 Types of Bonding 0:40:28 Empirical vs. Chemical Formulas 0:42:30 Cartoon: Ionic Bonds 0:43:28 Ionic Bonds 0:48:26 Charges of Atoms 0:50:50 Inert Pair Effect 0:51:36 Naming Ionic Compounds Required attribution: Brindley, Amanda Ph.D. General Chemistry 1A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1a_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US)

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Chem 125. Advanced Organic Chemistry. 26. Spin-Spin Coupling in 1H NMR Spectroscopy.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Chem 125. Advanced Organic Chemistry. 26. Spin-Spin Coupling in 1H NMR Spectroscopy. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Index of Topics: 0:00:30 Spin-Spin Coupling 0:12:55 Equal Couplings 0:20:15 Chemical Equivalence 0:28:15 Rotations 0:32:50 Example Spectra Recorded May 27, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Chem 125. Advanced Organic Chemistry. 25. NMR Spectroscopy: How NMR Works. Chemical Shifts.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Chem 125. Advanced Organic Chemistry. 25. NMR Spectroscopy: How NMR Works. Chemical Shifts. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Index of Topics: 0:02:20 Nuclear Spin and Dipoles 0:07:45 Boltzmann Distribution 0:19:00 NMR Spectrometer 0:28:00 NMR Spectrum 0:34:00 Absorbances of Protons 0:39:50 Concepts of Proton NMR 0:43:45 Chemical Shift Recorded May 25, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Chem 125. Advanced Organic Chemistry. 3. Databases and the Chemical Literature.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Lec 3. Databases and the Chemical Literature View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Index of Topics: 0:01:49 Journals 0:07:23 Databases 0:20:12 Journal of Organic Chemistry 0:25:27 Searching for a Compound 0:46:15 Problem 2.6 Recorded April 1, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Chem 125. Advanced Organic Chemistry. 27. Determining Stereochemistry and Regiochemistry by NMR.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Chem 125. Advanced Organic Chemistry. 27. Determining Stereochemistry and Regiochemistry by NMR. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Index of Topics: 0:00:55 Spin-Spin Coupling 0:11:15 sp2 Hybridization 0:31:40 Phenylacetylene Reaction Example 0:42:10 Long Range Coupling Recorded June 1, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 24.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 24. Inorganic Chemistry -- Coordination Chemistry II: Liquid Field Theory View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on December 1, 2014. Index of Topics: 00:07 - Adding Metal Electrons 04:42 - Electron Pairing Energy 10:48 - Using LFSE and Pi avg 13:41 - Metal-Ligand pi Interactions 17:02 - pi Donor vs pi Acceptor Ligands 25:48 - pi-Effects in Octahedral Complexes 36:05 - Spectrochemcial Series 41:18 - Angular Overlap Method 45:49 - ML6 Octahedral MO Diagram 46:51 - Using the AOM Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 107. Inorganic Chemistry. Lecture 27.

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UCI Chemistry: Inorganic Chemistry (Fall 2014) Lec 27. Inorganic Chemistry -- Coordination Chemistry III: Multi-Electron States View the complete course: http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html Instructor: Alan F. Heyduk. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry. Inorganic Chemistry (Chem 107) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 29-lecture undergraduate-level course titled "Inorganic Chemistry" taught at UC Irvine by Professor Alan F. Heyduk. Recorded on December 8, 2014. Index of Topics: 00:17 - Tackling the Multi-Electron Problem 01:52 - Multi-Electron Quantum Numbers 03:08 - V3+ Microstate Table 05:03 - Determining Atomic States 14:59 - Determining the Ground State 18:02 - Spin-Orbit Coupling 22:02 - Understanding the [V(OH2)6]3+ Spectrum 25:03 - Visualizing the 3F and 3P States 31:22 - Electronic State Diagram 35:43 - Visualizing the 3F and 3P States 42:36 - Electronic State Diagram Required attribution: Heyduk, Alan F. Inorganic Chemistry 107 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_107_inorganic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://www.creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Preparation for General Chemistry 1P. Lecture 01. Introduction.

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UCI Chem 1P General Chemistry Prep. (Fall 2012) Lec 01. General Chemistry Preparation for General Chemistry -- Introduction -- View the complete course: http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html Instructor: Eric Potma, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1P is a preparation go General Chemistry that covers: units of measurement, dimensional analysis, significant figures; elementary concepts of volume, mass, force, pressure, energy, density, temperature, heat, work; fundamentals of atomic and molecular structure; the mole concept, stoichiometry; properties of the states of matter; gas laws; solutions concentrations. Preparation for General Chemistry (Chem 1P) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 24-lecture undergraduate-level course titled "Preparation for General Chemistry" taught at UC Irvine by Associate Professor Eric Potma. Recorded on September 28, 2012. Slides: 00:07- Introduction 00:51- Your Instructor 02:03- This Quarter's Menu 04:25- What is Matter? 04:51- Zooming In 06:01- The World is Made of Molecules 06:35- Molecules Are Made of Atoms 06:45- Atom 07:26- Atoms are Real 09:00- Atoms are Small 12:08- Different Flavors 13:28- From Atoms to Molecules 14:22- Everything is Chemistry! 17:44- Chem 1P is Your Toolbox Required attribution: Potma, Eric General Chemistry 1P (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem 125. Advanced Organic Chemistry. 21. Benzoin & Acyloin Condensations. Acyl Anion Equivalents.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Lec 21. Benzoin & Acyloin Condensations. Acyl Anion Equivalents. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Index of Topics: 0:02:15 Carbon-Carbon Reaction Products 0:06:10 Umpolung Chemistry 0:19:30 O-Protected Cyanohydrins 0:29:48 1,3-Dithiane 0:42:10 Acyloin Condensation Recorded May 16, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Preparation for General Chemistry 1P. Lecture 09. Organic Compounds.

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UCI Chem 1P General Chemistry (Fall 2012) Lec 09. General Chemistry Preparation for General Chemistry -- Organic Compounds -- View the complete course: http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html Instructor: Eric Potma, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1P is a preparation go General Chemistry that covers: units of measurement, dimensional analysis, significant figures; elementary concepts of volume, mass, force, pressure, energy, density, temperature, heat, work; fundamentals of atomic and molecular structure; the mole concept, stoichiometry; properties of the states of matter; gas laws; solutions concentrations. Course may be offered online. Preparation for General Chemistry (Chem 1P) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 24-lecture undergraduate-level course titled "Preparation for General Chemistry" taught at UC Irvine by Associate Professor Eric Potma. Recorded on October 17, 2012. Slides: 00:05- Organic Compounds 02:54- Midterm 1 04:25- Organic Molecules, Covalent Bonds 06:29- Organic Chemistry 07:25- Why Carbon? 09:45- Alkanes 10:24- Common Bonding Patterns 14:29- Condensed Structural Formulas 17:25- Condensed Structural Formulas, Slide 2 21:56- Line Structures 25:15- Line Structures: Practice 27:41- Line Structures: Practice, Slide 2 31:01- Line Structures: Writing Formulas 34:00- Line Structures: Writing Formulas, Slide 2 35:42- An Exam Example 39:09- Bee Pheremones 40:10- Indigo 41:10- Steroids 42:02- The Pill 42:32- The Pill for Men 43:00- See You on Friday! Required attribution: Potma, Eric General Chemistry 1P (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem 125. Advanced Organic Chemistry. 28. 13C NMR Spectroscopy. Introduction to 2D NMR. COSY & HMQC.

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UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Chem 125. Advanced Organic Chemistry. 28. 13C NMR Spectroscopy. Introduction to 2D NMR. COSY & HMQC. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. Advanced Organic Chemistry (Chem 125) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Chemistry" taught at UC Irvine by Professor James S. Nowick. Recorded June 3, 2016. Required attribution: Nowick, James S., Advanced Organic Chemistry 125 (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html [Access date]. License: Creative Commons Attribution 3.0 United States License (http://creativecommons.org/licenses/by/3.0/us/deed.en_US).

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Preparation for General Chemistry 1P. Lecture 18. Acid-Base Reactions.

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UCI Chem 1P General Chemistry (Fall 2012) Lec 18. General Chemistry Preparation for General Chemistry -- Acid-Base Reactions -- View the complete course: http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html Instructor: Eric Potma, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1P is a preparation go General Chemistry that covers: units of measurement, dimensional analysis, significant figures; elementary concepts of volume, mass, force, pressure, energy, density, temperature, heat, work; fundamentals of atomic and molecular structure; the mole concept, stoichiometry; properties of the states of matter; gas laws; solutions concentrations. Course may be offered online. Preparation for General Chemistry (Chem 1P) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 24-lecture undergraduate-level course titled "Preparation for General Chemistry" taught at UC Irvine by Associate Professor Eric Potma. Recorded on November 16, 2012. Slides: 00:06- Acid-Base Reactions 01:37- Acids and Bases 03:39- Acids and Bases, Slide 2 05:12- Acids 08:25- Bases 10:29- Acid-Base Reactions: Hydrocholoric Acid and Potassium Hydroxide 15:53- Acid-Base Reactions: H+ and OH- 17:48- Acid-Base Reactions: Perchloric Acid and Magnesium Hydroxide 24:03- Titrations 25:22- Titrations: Neutralization Reaction 26:41- Youtube Example: Titration 28:06- Indicators 28:49- Indicators, Slide 2 29:52- Acid-Base Reactions: Neutralizing NaOH with HCl 35:35- Acid-Base Reactions: Hydrochloric Acid Added to BA(OH)2 Required attribution: Potma, Eric General Chemistry 1P (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1p_preparation_for_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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General Chemistry 1B. Lecture 3. Intermolecular Forces Liquids & Solids, Part III

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UCI Chem 1B General Chemistry (Winter 2013) Lec 03. General Chemistry Intermolecular Forces -- Liquids & Solids -- Part 3 View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: Donald R. Blake, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. General Chemistry (Chem 1B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 17-lecture undergraduate-level course titled "General Chemistry" taught at UC Irvine by Donald R. Blake, Ph.D. Recorded on January 15, 2013. Index of Topics 0:00:07 Transition from Liquids to Solids 0:12:34 Adhesion and Cohesion: Liquid/Liquid Forces 0:13:33 Adhesion and Cohesion: Liquid/Substrate 0:17:56 Surface Tension 0:18:29 Viscosity 0:21:04 Water 0:43:20 Quiz: Phase of Water 0:49:35 Quiz: Pressure in Flask 0:51:31 Cloud Formation/Dew Point 1:04:52 The Atmosphere: Temp vs Altitude 1:05:51 Stratospheric Chemistry 1:08:39 Interioinic and Intermolecular Interactions Required attribution: Blake, Donald R. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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