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Organic Chemistry 51A. Lecture 26. Regiochemical and Stereochemical Course of E2 Reactions.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 26. Organic Chemistry -- Regiochemical and Stereochemical Course of E2 Reactions View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded on December 2, 2009. Index of Topics: -0:50 Regiochemistry -1:32 2-bromobutene and NaOCH3 -3:42 Multiple Hydrogens -8:13 Zaitsev's Rule -12:37 Energy Diagram -18:33 Alkene Stereoisomers -27:54 Stereochemical Requirements for E2 Elimination -33:11 Stereoisomer Example -38:31 1,2-dibromo-1,2-diphenylethane Example -45:09 Newman Projections Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51A. Lecture 27. E1 Reactions. Comparison of SN1, SN2, E1, and E2 Reactions.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 27. Organic Chemistry E1 Reactions -- Comparison of SN1, SN2, E1, and E2 Reactions. View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded on December 4, 2009. Index of Topics: -0:37 Tert-Butyl Bromide Example -7:34 E1 Elimination -15:18 Energy Diagram for E1 -21:29 Tert-butanol and H2SO4 E1 Reaction -29:37 How Will an Alkyl Halide React? -33:45 Primary Alkyl Halides -37:35 Ethylbromide Example -43:32 Secondary Alkyl Halides -47:31 Good Nucleophiles Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51B. Lecture 23. Aromaticity.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 23. Organic Chemistry -- Aromaticity View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on March 8, 2013. Index of Topics: 00:11- Lake Elsinore toddler bitten by rattlesnake 00:54- Antivenom 05:00- 16.13: Drawing Bridged Bicyclic Products of Diels-Alder Reactions (corrected slide) 06:25- 17.7: Huckel's Rule-Recognizing Anti-aromatic Compounds 12:43- 17.7: Recognizing Anti-aromatic Compounds 18:13- 17.8C: How Do I Know if an atom is planar? 19:05- 17.8C: Aromatic Ions 26:29- 17.8C: How Do I Know if an atom is planar, revisited 29:56- 17.8D: Aromatic Heterocycles-Which lone pairs do I count? 38:45- 17.8B: Other Aromatic Compounds Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51C. Lecture 19. Organometallic Reactions in Organic Synthesis.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 19. Organic Chemistry -- Organometallic Reactions in Organic Synthesis -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on June 7, 2012 Index of Topics: 3:52-Grignard Reagent 7:01-Organometallic Complex 12:47-Organocopper Reagents 23:05-Organocuprate Mechanism 25:17-Stereospecificity 32:02-Drawbacks of Copper Chemistry 33:55-Suzuki Reaction 42:48-3 Main Steps to the Suzuki Mechanism 55:37-Using the Suzuki Reaction in Organic Synthesis 1:03:00-Olefin Metathesis 1:11:16-Partner Swapping Mechanism 1:15:20-Ring-Closing Metathesis Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 1

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 01. Organic Chemistry -- Introduction View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 5, 2015 Index of Topics: 03:27 - Course Info 14:34 - Alkyl Halides and Elimination Reactions 15:40 - Nucleophilic Substitution: Review 30:59 - Elimination Reaction 34:54 - Alkenes: Structure and Stability Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 2

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 02. Organic Chemistry -- Alkenes Structure and Stability View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 7, 2015 Index of Topics: 00:47 - Relative Stabilities of Alkenes 11:07 - The Mechanisms of Elimination 20:10 - The Effect of the Base 21:02 - Solvent Effects 24:24 - Leaving Group Effects 25:19 - Structure of the Substrate 33:35 - Regioselectivity of the E2 Reaction: The Zaitsev Rule Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51A. Lecture 02. Bond Polarity, Formal Charge, Lewis Structures

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 02. Organic Chemistry -- Bond Polarity, Formal Charge, Lewis Structures View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded September 28, 2009. Index of Topics: -2:48 Trends in Electronegativity -7:25 Examples of Polarity -15:00 Lewis Structures -22:12 Dimethyl Sulfoxide -30:15 Formal Charges -35:58 Formal Charges and Dimethyl Sulfoxide -41:00 Resonance Structures -48:12 Benzene Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 21.

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 21. Organic Chemistry -- Diels-Alder Reaction View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded March 2, 2015 Index of Topics: 00:49 - The Diels-Alder Reactions 01:32 - Characteristics of the Diels-Alder Reaction: Mechanism 02:10 - Substituent Effects 09:37 - Stereochemistry 18:41 - The Diels-Alder Reaction is Stereospecific 24:22 - The Endo Rule Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51A. Lecture 03. Resonance Structures, Skeletal Structures, Bond Length.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 03. Organic Chemistry -- Resonance Structures, Skeletal Structures, Bond Length View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded September 30, 2009. Index of Topics: -1:35 Skeletal Structures -9:57 Curved Arrow Notation -13:05 Curved Arrows and Benzene -19:39 Non-Equivalent Resonance Structures -26:36 Bond Lengths -46:52 Trifluoromethyl Cation Example Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51A. Lecture 04. Orbital Models of Structure and Bonding.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 04. Organic Chemistry -- Orbital Models of Structure and Bonding View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded October 2, 2009. Index of Topics: -0:55 Orbital-Based Models of Structure and Bonding -1:53 Molecular Orbitals -3:39 Orbitals of Molecular Hydrogen -10:36 Orbital Energy Diagram of Hydrogen -15:34 Hybrid Orbitals of Methane -22:09 Ethylene Orbitals -35:11 Acetylene Orbitals -39:39 Student Questions -43:20 Bond Strength Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51A. Lecture 05. Molecular Geometry, Acids and Bases.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 05. Organic Chemistry -- Molecular Geometry, Acids and Bases View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded October 5, 2009. Index of Topics: -1:29 Molecular Geometry - Bond Angle -3:12 sp3 Geometries -8:39 sp2 Geometries -14:50 sp Geometries -22:26 Chapter 2 -27:15 Bronsted-Lowry Acids and Bases -36:58 Ammonium Example -42:19 Acidity Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51B. Lecture 22. Conjugation, Resonance, Diels-Alder Reactions, Part 2.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 22. Organic Chemistry -- Conjugation, Resonance, Diels-Alder Reactions -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded March 6, 2013. Index of Topics: 00:13- A molecule today, a barrel tomorrow 00:42- Fracking 04:57- 16.12: The Diels-Alder Reaction 10:42- 16.13: Diene Requires an s-cis conformation 14:53- 16.13: Stereospecificity in the Diels-Alder Reaction 21:08- 16.13: Drawing Bridged Bicyclic Products of Diels-Alder Reactions 29:41- 16.13: The Endo Rule for Cyclic Dienes CHAPTER 17-Benzene and Aromatic Compounds 34:05- 17.1: The C=C pi bonds in benzene exhibit low reactivity 39:19- 17.3: Disubstituted benzene rings: ortho, meta, and para relationships 45:06- 17.4: C NMR Spectroscopy 47:14- 17.4: H NMR Spectroscopy Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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General Chemistry: Lec. 14. Corrections, Midterm Postmortem, Free Energy and Equilibrium

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UCI Chem 1B General Chemistry (Spring 2012) Lec 14. General Chemistry Intermolecular Forces -- Corrections, Midterm Postmorterm, Free Energy, and Equilibrium -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on May 24, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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General Chemistry: Lec. 15. One Midterm Problem, Free Energy & Equilibrium

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UCI Chem 1B General Chemistry (Spring 2012) Lec 15. General Chemistry -- One Midterm Problem, Free Energy and Equilibirum -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on May 29, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Organic Chemistry 51C. Lecture 16. Introduction to Carbohydrates: Structure and Stereochemistry.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 16. Organic Chemistry -- Introduction to Carbohydrates: Structure and Stereochemistry -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on May 29, 2012 Index of Topics: 3:12-Carbohydrates 8:39-Lactose 12:47-Subunits of Lactose 15:38-Alpha-D-Glucose 18:04-Anomers 21:51-Interconversion of Glucose Anomers 25:29-Interconverting Lactose? 28:26-Forms of Galactose 32:15-Optical Rotation 37:25-Chair Representation of Glucose 39:11-Haworth Representation of Glucose 42:40-Open Form Representation of Glucose 46:56-Fischer Projection 51:15-Converting Haworth Projection to a Fischer Projection 53:48-PyMOL Demonstration 1:02:49-Using Fischer Projections to Make Different Sugar Molecules 1:04:32-8 D Sugars Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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General Chemistry: Lec 6. Basic Properties of Solutions & Review Problems

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UCI Chem 1B General Chemistry (Spring 2012) Lec 06. General Chemistry Intermolecular Forces -- Basic Properties of Solutions and Review Problems -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 19, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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General Chemistry: Lec 5. Phase Diagrams and Phase Transitions

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UCI Chem 1B General Chemistry (Spring 2012) Lec 05. General Chemistry -- Phase Diagram and Phase Transitions -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 17, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Organic Chemistry 51C. Lecture 02. Reactivity of Carbonyl Compounds.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 02. Organic Chemistry -- Reactivity of Carbonyl Compounds -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 5, 2012 Index of Topics: -1:00 Reactivity with Nucleophilic -4:08 Resonance in a Carbonyl group -8:41 Nucleophiles and Carbonyls -18:09 LiAlH4 and NaBH4 -26:29 Example Reaction -32:38 Reduction -44:10 Hydride Reducing Agents -48:57 Sodium Hydride -54:02 Oxidation State -1:00:14 Reactivity Toward Nucleophiles -1:08:44 Making Racemic Mixtures -1:12:38 Chiral Hydride Reagent -1:16:05 Tert-Butyl Cyclohexanone Example Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 21: Acidity & Basicity of Amines

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 21. Organic Chemistry -- Acidity & Basicity of Amines View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded May 18, 2015 Index of Topics: 01:04 - Famous Amines 03:13 - Reaction of an Amine as a Base 05:29 - Reaction of an Amine as an Acid 06:37 - Substituent Effects on Amine Acidity and Basicity 32:44 - Acidity & Basicity of Aromatic Heterocycles Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51C. Lecture 05. Aldehydes and Ketones: Reactions.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 05. Organic Chemistry -- Aldehydes and Ketones: Reactions -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 17, 2012 Index of Topics: 1:08-Carbonyls and Strongly Basic Nucleophiles 4:01-Weakly Basic Nucleophiles 9:56-Naming Carbonyls 14:22-Properties of Ketones and Aldehydes 16:59-Reactivity 19:38-IR Spectroscopy 26:04-Conjugation 32:12-NMR 37:52-Synthesis of Aldehydes and Ketones 47:14-Reactions with Nucleophiles 54:25-Acetylene and Hydrogen Cyanide Examples 1:00:16-Workup of Cyanide Anion Addition 1:04:15-Wittig Reaction 1:09:44-Wittig Reaction Mechanism 1:16:24-Making a Wittig Reagent 1:18:14-Wittig Reaction Examples 1:20:11-Stereoselectivity Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 15: Alternatives to Direct Alkylation of Enolate Ions

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 15. Organic Chemistry -- Alternatives to Direct Alkylation of Enolate Ions View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded May 4, 2015 Index of Topics: 00:21 - Base Promoted Halogenation of Aldehydes and Ketones 11:46 - Alpha Halogenated Carbonyl Compounds in Synthesis 17:55 - Direct Alkylation of Enolate Ions 27:44 - Kinetic vs Thermodynamic Enolate 43:45 - Alkylation and Acylation of the Alpha Carbon via an Enamine Intermediate Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51C. Lecture 07. Acid-Catalyzed Formation of Hydrates, Hemiacetals, & Acetals.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 07. Organic Chemistry -- Acid-Catalyzed Formation of Hydrates, Hemiacetals, & Acetals -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 24, 2012 Index of Topics: 1:19-Electrophilicity of Aldehydes and Ketones 5:37-Hydrates 12:17-Acid-Catalyzed Addition of Water to Acetone 21:29-Acetone Enol Example 24:01-Reverse Reaction 25:31-Energy Diagram 29:28-Reverse Reaction Mechanism 36:38-Acid-Catalyzed Acetal Formation 40:00-Hemiacetal 43:01-Strong Acid 47:23-Hemiacetal Formation Mechanism 50:52-Hemiacetal to Acetal Mechanism 1:00:52-Acid-Catalyzed Acetal Hydrolysis 1:06:12-Protecting Groups 1:12:15-Cyclic Hemiacetal Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51B. Lecture 10. Alkynes, Part 2.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 10. Organic Chemistry -- Alkynes -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on January 30, 2013. Index of Topics: 00:10- Gatorade to remove controversial ingredient 02:36- Soybean oil vs. brominated vegetable oil 05:20- 11.2,11.3,11.4: Names, Properties, Examples 11:00- 11.5: Make Alkynes Through Dehydrohalogenation 16:48- 11.5: Super Basic Condns 22:29- 11.5: Make Alkynes Through Dehydrohalogenation 26:38- 11.6: Alkyne Reactivity 30:54- 11.6: Alkyne Reactivity, Slide 2 34:13- 11.7: Addition of HX to Alkynes 37:17- 11.7: Addition of HX to Alkynes, Slide 2 41:24- 11.7: Addition of HX to Vinyl Halides For more information and access to courses, lectures, and teaching material, please visit the official UC Irvine OpenCourseWare website at: http://ocw.uci.edu

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Chem 51C. Organic Chemistry. Lec. 06: Alpha-Beta Unsaturated Carbonyl Compounds

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 06. Organic Chemistry -- ?,?-Unsaturated Carbonyl Compounds View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 10, 2015 Index of Topics: 00:34 - Typical Reaction with Type 2 Carbonyl 05:17 - Grignard Reagents to Synthesize Carboxylic Acids 10:49 - Summarizing Grignard Reagents, Organolithium Reagents & Cuprates 14:29 - Grignards & Organolithium Reagents do not react with Alkyl Halides 15:54 - Cuprates have their own unusual chemistry 19:12 - Alpha, Beta Unsaturated Carbonyl Compounds 24:53 - Conjugate Addition competes with Addition to the Carbonyl 33:36 - Protecting Groups in Synthesis 41:24 - Designing Synthesis Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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General Chemistry: Lec 7. Solutions and Colligative Properties

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UCI Chem 1B General Chemistry (Spring 2012) Lec 07. General Chemistry -- Solutions and Colligative Properties -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 26, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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