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Organic Chemistry 51C. Lecture 09. Reactions of Carboxylic Acids, Esters, Amides, & Nitriles.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 09. Organic Chemistry -- Reactions of Carboxylic Acids, Esters, Amides, & Nitriles -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on May 1, 2012 Index of Topics: 0:56-Esters and Carboxylic Acids Reactivity 9:29-Fischer Esterification 16:41-Fischer Esterification Mechanism 29:52-Hydrolysis of Esters 32:13-Saporification 37:27-Amides and Nitriles 53:36-Making Acid Chlorides 58:11-Making Amides 1:01:33-Nitriles and LiAlH4 and other Organometallic Reagents Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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General Chemistry: Lec 8. Osmotic Pressure, Colloids & Sum Up of Colligative Properties

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UCI Chem 1B General Chemistry (Spring 2012) Lec 08. General Chemistry -- Osmotic Pressure, Colloids & Sum Up of Colligative Properties -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on May 1, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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General Chemistry: Lec. 9. Thermochemistry: Work, Heat, & First Law of Thermodynamics

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UCI Chem 1B General Chemistry (Spring 2012) Lec 09. General Chemistry -- Thermochemistry: Work, Heat, and the First Law of Thermodynamics -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on May 3, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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General Chemistry: Lec. 10. Thermochemistry: Work, Heat, Enthalpy and Heat Capacity

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UCI Chem 1B General Chemistry (Spring 2012) Lec 10. General Chemistry -- Work, Heat, Enthalpy and Heat Capacity -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on May 8, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Organic Chemistry 51C. Lecture 10. Enols and Enolates.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 10. Organic Chemistry -- Enols and Enolates -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on May 3, 2012 Index of Topics: 1:16-Reactivity of Ketones 3:02-Enols 6:36-Enolate Anion 9:47-Enolates and Electrophiles 16:49-Equilibrium Between Tautomers 23:07-Acid-Catalyzed Enol Formation 29:18-Energy Diagram 37:51-Multiple Additions 46:41-pKa of Alpha Protons 53:05-Base-Catalyzed Enol Formation 58:56-Stereochemistry 1:03:42-LDA 1:11:28-Kinetic Product vs Thermodynamic Product 1:17:56-LDA and Stereochemistry Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51C. Lecture 11. More Reactions of Enols and Enolates.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 11. Organic Chemistry -- More Reactions of Enols and Enolates -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on May 10, 2012 Index of Topics: 1:05-Enolates 3:57-Enolates and Electrophiles 9:11-Alpha-Halogenation of Ketones and Aldehydes 13:58-Halogenation Mechanism 21:58-Halogenation Example 25:10-Alpha-Halogenation Promoted by Base 35:29-Haloform Reaction 39:02-Haloform Reaction Mechanism 43:37-pKa Values 53:20-Reason for Acidity 1:00:35-AcetoAcetic Ester Synthesis 1:10:36-Malonic Ester Synthesis 1:14:44-Example Problem Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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General Chemistry 1B. Lec 1. General Course Information & Properties of Gas.

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UCI Chem 1B General Chemistry (Spring 2012) Lec 01. General Chemistry -- General Course Information & Properties of Gases -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 10, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Chem125. Advanced Organic Chemistry. Lecture 8. Reaction Kinetics.

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This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Spectroscopy" taught at UC Irvine by Professor James S. Nowick. The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. The course follows closely to the textbook Intermediate Organic Chemistry, 3rd edition, by Ann M. Fabirkiewicz and John C. Stowell. The course website is: https://eee.uci.edu/16s/40914/ Any questions or concerns regarding this class, please e-mail: jsnowick@uci.edu. Recorded on April 13, 2016

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Organic Chemistry 51C. Lecture 03. Reactions of Organometallic Reagents.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 03. Organic Chemistry -- Reactions of Organometallic Reagents -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 12, 2012 Index of Topics: -1:36 Ketone/Aldehyde Reduction -5:56 Grignard Reagents -12:31 Polarity of Grignard Reagent -16:01 Basicity of Grignard Reagent -19:22 Grignard Reagents and Water/Alcohol -21:32 Organolithium Reagent -25:50 Acetylide Anions -34:07 Making Acetylide Anion -38:29 Reactivity of the Carboxylic Acid Family -44:56 Addition-Elimination Reaction -48:12 Examples of Carboxylic Acid Reduction -53:29 Multiple Additions onto Carboxylic Acids -59:50 Leaving Groups -1:08:27 Synthesizing Example -1:16:54 More Examples of Synthesizing Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem125. Advanced Organic Chemistry. Lecture 9.Reaction Rates and the Eyring Equation.

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This video is part of a 28-lecture junior/senior-level undergraduate-level course titled "Advanced Organic Spectroscopy" taught at UC Irvine by Professor James S. Nowick. The course builds upon the concepts and skills learned in a typical yearlong sophomore-level organic chemistry class. Topics include: The Chemical Literature and Databases; Stereochemistry and Structural Organic Chemistry; Synthetic Organic Chemistry; Mechanistic and Physical Organic Chemistry; NMR Spectroscopy. The course follows closely to the textbook Intermediate Organic Chemistry, 3rd edition, by Ann M. Fabirkiewicz and John C. Stowell. The course website is: https://eee.uci.edu/16s/40914/ Any questions or concerns regarding this class, please e-mail: jsnowick@uci.edu. Recorded on April 15, 2016.

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General Chemistry: Lec 3. Last Gas(p) and Condensed Phases

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UCI Chem 1B General Chemistry (Spring 2012) Lec 03. General Chemistry -- Last Gas (p) and Condensed Phases -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 10, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Chem 51C. Organic Chemistry. Lec. 02: Preparation of Carboxylic Acids

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 02. Organic Chemistry -- Preparation of Carboxylic Acids View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 1, 2015 Index of Topics: 00:43 - Oxidation of Alkyl Groups Bonded to Aromatic Rings 03:31 - Sulfonic Acids 09:33 - Reactivity of Carbonyl Compounds 11:57 - Type 1 of Carbonyl Compounds 15:01 - Type 2 of Carbonyl Compounds 16:14 - Both Type 1 and Type 2 Carbonyl Compounds are Electrophilic 32:46 - Both Type 1 and Type 2 Carbonyl compounds are weakly basic at the carbonyl oxygen and protonated by strong acids 41:07 - Both Type 1 and Type 2 carbonyl compounds are acidic 44:24 - Reactivity of the various Type 1 and Type 2 Carbonyl Compounds Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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General Chemistry: Lec 4. Condensed Phases, Solids, & Phase Diagrams

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UCI Chem 1B General Chemistry (Spring 2012) Lec 04. General Chemistry Intermolecular Forces -- Condensed phases, solids, and phase diagrams -- View the complete course: http://ocw.uci.edu/courses/chem_1b_general_chemistry.html Instructor: A.J. Shaka. Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Recorded on April 12, 2012. Required attribution: Shaka, A.J. General Chemistry 1B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_1b_general_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License

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Organic Chemistry 51C. Lecture 04. Reactions and Protecting Groups.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 04. Organic Chemistry -- Reactions and Protecting Groups -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 12, 2012 Index of Topics: -3:09 Carboxylic Acids and LiAlH4 -9:07 DIBAL-H -14:59 Multiple Equivalents of Organometallic Reagents -18:18 Organocuprate Reagent -22:11 Chemoselectivity -26:14 Reducing Carbonyls and Alkenes -30:48 Oxidizing Agents -33:31 Regioselectivity -36:10 Resonance -40:00 Enones and Nucleophiles -41:45 Enolate Anion -44:15 Tautomerization -45:53 Protecting Groups -50:40 Taking the Protecting Groups Off -56:32 Synthesizing -1:05:33 Corrections Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51C. Lecture 06. Formation of Imines & Enamines from Aldehydes & Ketones.

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UCI Chem 51C Organic Chemistry (Spring 2012) Lec 06. Organic Chemistry -- Formation of Imines & Enamines -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on April 19, 2012 Index of Topics: 4:10-HCN Addition and Wittig Reaction 7:13-Ketones or Aldehydes and Amines 10:32-Aldimine Formation Example 15:23-Ketimine Formation Example 19:55-Mechanism of Acid-Catalyzed Imine Formation 33:28-Acid-Catalyzed Breakdown of the Hemiaminal 44:33-Answer to Student Question 47:50-Imine Formation 49:49-Reversibility 53:15-Example of Reversibility 55:50-Enanamines 59:04-Nucleophilicity of Amine 1:01:50-Imine Reaction with Base Required attribution: Nowick, James S. Organic Chemistry 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 12: Reactions of Carboxylic Acids

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 12. Organic Chemistry -- Reactions of Carboxylic Acids View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 27, 2015 Index of Topics: 00:20 - Reaction of Esters with Alcohols: Transesterification 02:03 - Reaction of Esters with Amines: Aminolysis 02:37 - Reactions of Carboxylic Acids 07:09 - Acid Catalyzed Esterification (Fisher Esterification) 14:30 - Conversion of Carboxylic Acids into Acid Chlorides 21:51 - Reactions of Amides 22:44 - Acid Catalyzed Hydrolysis of Amides 31:32 - Acid Catalyzed Esterification 32:14 - Reactions of Nitriles 45:12 - Irreverisble Addition Reactions of Type 2 Carbonyl Compounds Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 13: Substitution Reactions of Carbonyl Compounds at the ?-Carbon

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 13. Organic Chemistry -- Substitution Reactions of Carbonyl Compounds at the Alpha-Carbon View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 29, 2015 Index of Topics: 00:21 - Irreversible Addition Reactions of Type 2 Carbonyl Compounds 17:31 - Acidity of Alpha Hydrogens 19:50 - Why is the Alpha Hydrogen of a Carbonyl Acidic? 34:02 - Enolization of Carbonyl Compounds 40:33 - What Determines the Percentage of Enol at Equilibrium? Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 07: Aldehydes & Ketones: Nucleophilic Substitution

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 07. Organic Chemistry -- Aldehydes & Ketones: Nucleophilic Substitution View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 13, 2015 Index of Topics: 01:51 - Designing Syntheses 10:17 - Some Famous Type 1 Carbonyl Compounds 12:23 - Physical Properties of Aldehydes & Ketones 15:24 - Reversible Addition Reactions of Aldehydes & Ketones 16:05 - Addition of Water (Hydration) 37:24 - Base Catalyzed Addition of Alcohols 41:11 - Acid Catalyzed Addition of Alcohols 43:54 - Step 1: Hemiacetal Formation 46:30 - Step 2: Acetal Formation Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 05: Addition of Organometallic Reagents to Carbonyls

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 05. Organic Chemistry -- Addition of Organometallic Reagents to Carbonyls View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 8, 2015 Index of Topics: 00:26 - Addition of Carbon Nucleophiles 04:54 - Preparation of Organometallic Reagents 11:09 - Organometallic reagents are powerful bases 14:34 - Acidic groups that interfere with Grignard Formation 19:46 - Organometallic Reagents are Powerful Nucleophiles 24:57 - Typical Reaction with Type 1 Carbonyl 31:38 - Typical Reaction with Type 2 Carbonyl Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 26: Oxidation Reactions of Sugars

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 26. Organic Chemistry -- Oxidation Reactions of Sugars View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded June 3, 2015 Index of Topics: 00:50 - Ether Formation 04:09 - Esterification 06:02 - Biosynthesis of Glucose 6 Phosphate 06:46 Reducing vs Non-reducing Sugars 11:48 - Oxidizing Agent: Tollen's Reagent 15:11 - Oxidizing Agent: Bromine/H2O 21:57 - Oxidizing Agent: Nitric Acid 24:13 - The Killiani Fisher Synthesis 30:52 - The Ruff Degradation 39:30 - Reduction Reactions of Sugars 41:22 - Disaccharides Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 14: Reactions at the Alpha-Carbon

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 14. Organic Chemistry -- Reactions at the Alpha-Carbon View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded May 1, 2015 Index of Topics: 00:21 - What Determines the Percentage of Enol at Equilibrium? 05:30 - How would you completely deprotonate acetone? 10:27 - Mechanism of Keto-Enol Tautomerization: Base Catalyzed 15:55 - Mechanism of Keto-Enol Tautomerization: Acid Catalyzed 24:07 - Reactions at the Alpha-Carbon 26:39 - Racemization 31:38 - Deuterium Exchange 36:54 - Acid Catalyzed Halogenation of Aldehydes and Ketones 41:07 - Base Promoted Halogenation of Aldehydes and Ketones Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 01: Carboxylic Acids

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 01. Organic Chemistry --Carboxylic Acids & the Acidity of the O-H Bond View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded March 30, 2015 Index of Topics: 00:08 - Structure and Physical Properties of Carboxylic Acids 09:33 - Acidity of Carboxylic Acids 32:37 - Common Bases to Deprotonate Carboxylic Acids 36:48 - Oxidation of Aldehydes and 1 Alcohols 37:48 - Oxidative Cleavage of Alkenes & Alkynes: Ozonolysis Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 03: Hydride Reagents and Addition to Carbonyls

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 03. Organic Chemistry -- Hydride Reagents and Addition to Carbonyls View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 3, 2015 Index of Topics: 01:59 - Reactivity of Various Type 1 and Type 2 Carbonyl Compounds 03:09 - Order of Resonance Stabilization 16:13 - Irreversible Addition Reactions of Type 1 and Type 2 Carbonyls 24:50 - Addition of Hydride Reagents Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 04: Hydride Reagents and Addition to Carbonyls Part 2

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 04. Organic Chemistry -- Hydride Reagents and Addition to Carbonyls -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded April 6, 2015 Index of Topics: 00:24 - Alkoxide Leaving Group 01:39 - Points about Hydride Additions to Carbonyls 06:38 - LiAlH4 adds twice to Acid Chlorides 14:32 - Exactly Reducing Acid Chlorides to Aldehydes 17:59 - LiAlH4 Reduces Carboxylic Acids to Alcohols 26:43 - Converting a Carboxylic Acid to an Aldehyde 28:18 - Reducing Amides to Amines 38:33 - Stereochemistry of Carbonyl Reduction 40:21 - Chiral Reducing Agents 45:18 - Addition of Carbon Nucleophiles: Organometallic Reagents Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chem 51C. Organic Chemistry. Lec. 27: Polysaccharides

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UCI Chem 51C: Organic Chemistry (Spring 2015) Lec 27. Organic Chemistry -- Polysaccharides View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51C) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded June 5, 2015 Index of Topics: 00:20 - Reduction Reactions of Sugars 02:55 - Disaccharides 10:03 - Cellulose 12:14 - Starches 16:25 - Sweeteners, Fats, and Drugs Derived from Sugars 29:46 - Amino Sugars 30:36 - N Glycosides Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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