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Organic Chemistry 51B. Lecture 16. Infrared Spectroscopy + Ch. 14.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 16. Organic Chemistry -- Infrared Spectroscopy and Chapter 14 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded February 15, 2013. Topics Covered: Infrared Spectroscopy and Chapter 14. Index of Topics: 00:09- Superomniphobic material 01:47- Underlying Molecules CHAPTER 13- Mass Spectrometry and Infrared Spectroscopy 04:42- 13.1: The Mass Spectrometer-how does it work? 09:26- 13.1-13.3: Mass spectra are complex due to fragmentation 11:55- 13.4: The Exact Mass gives the Molecular Formula 15:14- 10.2: Use the Molecular Formula to determine Degree of Unsaturation 19:25- 13.5: Electromagnetic Radiation and Infrared 22:45- 13.6: Dumb Characteristics of an IR spectrum 26:56- 13.6: Key Frequency Regions of the IR spectrum 32:22- 13.6: Practice: Regions of the IR spectrum 34:58- 13.6,7: Polar Bonds Lead to Intense Peaks 39:35- 13.7: Hydrogen bonding leads to lumpy peaks 42:06- 13.6: Dumb Characteristics of an IR spectrum (revisited) 42:44- 13.6,7: Check if C-H stretches are above or below 300 cm^(-1) 46:00- Reading Spectra Examples Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51B. Lecture 18. NMR Spectroscopy, Part 2.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 18. Organic Chemistry -- NMR Spectroscopy -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded February 22, 2013. Index of Topics: 00:13- Hash Oil 01:25- Structure of tetrahydrocannaboil 04:02- 14.11, 14.12: C NMR Chemical Shift Ranges 11:20- 14.11, 14.12: Practice Using C NMR Chemical Shift Ranges 15:40- 14.2: How many signals should I expect in the H spectrum? 20:46- 14.2: Diastereotopic or Enantiotopic Protons? Use the Z-test 27:19- 14.2: Use the Z-test, Slide 2 29:58- 14.3B: H NMR Chemical Shift Ranges 39:27- 14.3A, 14.4: Shielding and Deshielding Effects-anisotropy 42:23- 14.3A, 14.4: Shielding and Deshielding Effects-proximity to the pi system 46:03- 14.3A, 14.4: Sheilding and Deshielding Effects-electronegative atoms 48:32- 14.5: Integration of H NMR Peaks Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 25

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 25. Organic Chemistry -- Substituent Effect and Friedal-Crafts Reactions View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded March 11, 2015 Index of Topics: 00:43 - Ring Activating 07:06 - Ring Deactivating 15:57 - Effect of Sterics and More than One Substituent 21:19 - Methoxy, Hydroxy, and Amine Substituents 29:41 - Friedel-Crafts Alkylation & Acylation 42:19 - Nitration of Aniline Derivatives Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51B. Lecture 13. Reduction and Oxidation, Part 1.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 13. Organic Chemistry -- Reduction and Oxidation -- Part 1 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on February 8, 2013. Index of Topics: 00:10- Imitation Vanilla 01:13- 'Vanilla Extract' produced in Mexico is no bargain 02:09- The Tonka Bean 03:30- Structure of Vanillin vs. Coumarin CHAPTER 12-Oxidation and Reduction 05:52- 12.1: Introduction 12:42- 12.2: Secret "Hydride" Reducing Agents from Ch 20 15:54- 12.2: Other Reducing Agents 19:20- 12.3,12.4: Hydrogenation of Alkenes 25:12- 12.3,12.4: Hydrogenation of Alkenes-Benzene rings, C=C bonds 29:37- 12.5A,B: Partial Hydrogenation of Alkynes 32:20- 12.5 A,B: Hydrogenation of Alkynes 37:17- 12.5C: Partial Hydrogenation of Alkynes to Alkenes 42:57- 12.5C: Dissolving metal reduction Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Organic Chemistry 51B. Lecture 14. Reduction and Oxidation, Part 2.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 14. Organic Chemistry -- Reduction and Oxidation -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on February 11, 2013 Index of Topics: 00:09- Vanillin Stain 03:16- Various Dip Stains 06:53- 12.5C: Partial Hydrogenation of Alkynes to Alkenes 08:23- 12.5C: Dissolving metal reduction 13:58- 12.6: the Reductive Opening of Epoxides 19:00- 12.8: Epoxidation of C=C with mCPBA 23:28- 12.8: Epoxidation of C=C with mCPBA-stereospecific 25:59- 12.8: Epoxidation of C=C with m-CPBA-draw all substituents 28:06- 12.9A: Two-Step Anti-Dihydroxylation 31:51- 12.9B: Syn-Dihydroxylation 37:33- 12.9B: Syn-Dihydroxylation, Slide 2 Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 12

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 12. Organic Chemistry -- Addition of Borane View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 4, 2015 Index of Topics: 00:09 - Addition of Bromine and Chlorine to Alkenes 07:43 - How is the enantiomer formed? 13:11 - Important points about halogen reaction 22:52 - Regiochemistry in this addition 29:14 - Addition of Borane: Hydroboration/Oxidation Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 13

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 13. Organic Chemistry -- Reactions, Synthesis, & Alkynes View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 6, 2015 Index of Topics 01:12 - Addition of Borane: Hydroboration/Oxidation 08:52 - Stereoselectivity in Hydroboration Reactions 14:27 - Reactions and Synthesis 32:29 - Alkynes: Introduction 39:29 - Nomenclature 45:08 - Acidity of 1-Alkynes Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 14

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 14. Organic Chemistry -- Electrophilic Addition Reactions of Alkynes View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 9, 2015 Index of Topics: 01:15 - Sample Flashcards 05:33 - Acidity and s Character 14:59 - Relative Acidities 16:32 - Some Reactions after Deprotonation 21:50 - Preparation of Alkynes 30:54 - Addition of Hydrogen Halides to Alkynes 41:59 - Addition of Water to Alkynes: Hydration Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 15

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 15. Organic Chemistry -- Tautomerization, Oxidation, and Reduction View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 11, 2015 Index of Topics: 00:54 - Mechanism of Hydration 07:13 - Important points about Hydration 12:03 - Addition of Bromine and Chlorine to Alkynes 15:08 - Hydroboration/Oxidation of Alkynes 28:59 - Designing Synthesis: Part 1 37:10 - Introduction: Oxidation & Reduction 38:19 - Recognizing Oxidation and Reduction of Organic Compounds 47:20 - Reduction Reactions 48:55 - Addition of Hydrogen to Alkenes Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 16

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 16. Organic Chemistry -- Oxidation Reactions View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 13, 2015 Index of Topics: 00:08 - Addition of Hydrogen to Alkenes 09:17 - Hydrogenation of Other Double Bonds 12:29 - Reduction of Alkynes 17:44 - Linlar's Catalyst 20:10 - The Reduction of Polar C-X sigma bonds 29:24 - Oxidation Reactions: Oxidizing Agents 31:44 - Epoxidation 39:49 - Sharpless Asymmetric Epoxidation 43:50 - Dihydroxylation Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 26

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 26. Organic Chemistry -- Synthetic Applications of Electrophile Aromatic Substitution View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded March 13, 2015 Index of Topics: 00:50 - Reactions of Substituents on Benzene 02:17 - Reactions of Alkyl Substituents on Benzne 04:36 - Oxidation of Alkyl Groups Bonded to Aromatic Rings 07:36 - Reduction of Substituents Bonded to Benzene 09:54 - Clemmensen Reduction (HCl, Zn/Hg) 11:23 - Wolff-Kishner Reduction (H2NNH3, KOH) 14:23 - Nucleophilic Aromatic Substitution via Addition/Elimination 14:50 - Synthetic Applications of Electrophilic Aromatic Substitution Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 18

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 18. Organic Chemistry -- Radical Reactions View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 20, 2015 Index of Topics: 01:30 - General Features of Radical Reactions 01:54 - Reaction of a Radical X with a C-H Bond 03:47 - Reaction of a Radical X with a C=C Bond 04:58 - Radical Mechanisms 06:40 - Halogenation of Alkanes 09:16 - Mechanism 1 27:05 - Mechanism 2 31:24 - Selectivity and Stability 43:52 - Radical Substitution of Benzylic and Allylic Hydrogens Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 19

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 19. Organic Chemistry -- Stereochemistry of Radical Reactions & Free Radical Oxidation View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 23, 2015 Index of Topics: 00:57 - Radical Substitution of Benzylic and Allylic Hydrogens 05:05 - Stereochemistry of Radical Reactions 13:10 - Radical Addition of HBr to an Alkene 24:57 - Radical Initiators 26:12 - The Peroxide Effect 30:06 - Autooxidation 37:46 - Preventing Autooxidation: Addition of Antioxidants (Free-Radical Scavengers) 39:20 - Conjugation Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 20.

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 20. Organic Chemistry -- Conjugation, Resonance, and Dienes View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded February 25, 2015 Index of Topics: 02:39 - Conjugation 03:29 - Conformations of Conjugated Dienes 16:27 - Electrophilic Addition Reactions of Isolated Dienes 19:49 - Electrophilic Addition Reactions of Conjugated Dienes: 1,2 and 1,4 Additions 30:02 - Kinetic vs Thermodynamic Products 42:12 - The Diels-Alder Reactions Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51B. Lecture 24. Electrophilic Aromatic Substitution.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 24. Organic Chemistry -- Electrophilic Aromatic Substitution -- Part 1 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on March 11, 2013. Index of Topics: 00:36- Natural Does Not Mean Safe 01:43- Molecular structure of allantoin CHAPTER 18-Electrophilic Aromatic Substitution=E.A.S. 04:00- Chapter 18 Introduction 08:51- 18.1: Five Important Electrophilic Aromatic Substitution Reactions 14:39- 18.2: Two-Step Mechanism for E.A.S. 22:33- 18.3: Dalogenation with FeX3 and X2 31:05- 18.4: Nitration with HNO3 and H2S04 39:48- 18.4: Sulfation with SO3 and H2SO4 45:56- 18.5: Friedel-Crafts Acylation with RCOCl and AlCl3 Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 3

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 03. Organic Chemistry -- Stereochemistry of Elimination Reactions View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 9, 2015 Index of Topics: 00:08 - Regioselectivity of the E2 Reaction: The Zaitsev Rule 07:51 - The Stereochemistry of the E2 Reaction Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 4

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 04. Organic Chemistry -- Unimolecular Elimination View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 12, 2015 Index of Topics: 00:11 - The Stereochemistry of the E2 Reaction 08:23 - Competition between Sn2 vs E2 28:43 - Rate Law and Mechanism of the E1 Reaction Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 5

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 05. Organic Chemistry -- E1 Mechanism & Double Elimination View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 14, 2015 Index of Topics: 01:12 - Alkene Model 04:19 - Rate Law and Mechanism of the E1 Reaction 06:13 - Energy Diagram for an E1 Reaction 09:01 - Important points on E1 Reaction 11:27 - Examples of E1 Reactions 18:30 - Competition between SN1 and E1 23:25 - Kinetic Isotope Effect 27:53 - Double Elimination 37:27 - Elimination Reaction Handout 42:35 - Animations Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51B. Lecture 25. Electrophilic Aromatic Substitution Part 2.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 25. Organic Chemistry -- Electrophilic Aromatic Substitution -- Part 2 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded March 13, 2013. Index of Topics: 00:10- Red Tide Kills Record Number of Manatees 01:02- Molecular structure of brevetoxin A 02:56- 18.1: Five Important Electrophilic Aromatic Substitution Reactions 04:21- 18.5: Friedel-Crafts Alkylation with AlCl3 and Alkyl halides 09:37- 18.5: Friedel Crafts Alkylation without 14:32- 18.6, 18.7, 18.8: Substituents Affect Rates and Regiochemistry in E.A.S. 20:43- 18.9: Compare Arenium Ions to Explain Regiochemistry 26:41- 18.6: Substituents that favor ortho, para substitution 31:13- 18.6: Substituents that favor meta substitution 35:56- 18.6: L.P. Resonance Donor Effects Outcompete Inductive Effects 40:32- 18.7: Summary of EAS Substituent Effects-Know This Summary 45:43- 18.10: Special Rules for Friedel-Crafts Reactions 46:33- 18.9: Don't Confuse the directing group with the new substituent 49:58- 18.10: Special Rules fro Friedel-Crafts Reactions (revisited) Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Kinetics (MIT) Kinetics (MIT)

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This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions.AcknowledgementsThe material for 5.60 has evolved over a period of many years, and therefore several faculty members have contributed to the development of the course contents. The following are known to have assisted in preparing the lecture notes available on OCW:Emeritus Professors of Chemistry: Robert A. Alberty, Carl W. Garland, Irwin Oppenheim, John S. Waugh.Professors of Chemistry: Moungi Bawendi, John M. Deutch, Robert W. Field, Robert G. Griffin, Keith A. Nelson, Robert J. Silbey, Jeffrey I. Steinfeld.Professor of Bioengineering and Computer Science: Bruce Tidor.Professor of Chemistry, Ri This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions.AcknowledgementsThe material for 5.60 has evolved over a period of many years, and therefore several faculty members have contributed to the development of the course contents. The following are known to have assisted in preparing the lecture notes available on OCW:Emeritus Professors of Chemistry: Robert A. Alberty, Carl W. Garland, Irwin Oppenheim, John S. Waugh.Professors of Chemistry: Moungi Bawendi, John M. Deutch, Robert W. Field, Robert G. Griffin, Keith A. Nelson, Robert J. Silbey, Jeffrey I. Steinfeld.Professor of Bioengineering and Computer Science: Bruce Tidor.Professor of Chemistry, Ri

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thermodynamics | thermodynamics | kinetics | kinetics | equilibrium | equilibrium | macroscopic systems | macroscopic systems | state variables | state variables | law of thermodynamics | law of thermodynamics | entropy | entropy | Gibbs function | Gibbs function | reaction rates | reaction rates | clapeyron | clapeyron | enthalpy | enthalpy | clausius | clausius | adiabatic | adiabatic | Hemholtz | Hemholtz | catalysis | catalysis | oscillators | oscillators | autocatalysis | autocatalysis | carnot cycle | carnot cycle

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Content within individual OCW courses is (c) by the individual authors unless otherwise noted. MIT OpenCourseWare materials are licensed by the Massachusetts Institute of Technology under a Creative Commons License (Attribution-NonCommercial-ShareAlike). For further information see http://ocw.mit.edu/terms/index.htm

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Chemistry 51B: Organic Chemistry. Lecture 6

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 06. Organic Chemistry -- Alcohols, Ethers, and Epoxides View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 16, 2015 Index of Topics: 00:47 - Introduction 04:15 - Nomenclature of Alcohols 10:47 - Nomenclature of Ethers 14:59 - Preparation of Alcohols, Ethers, Epoxides 34:06 - Elimination Reactions of Alcohols: Dehydration Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51B. Lecture 26. Electrophilic Aromatic Substitution, Part 3.

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UCI Chem 51B Organic Chemistry (Winter 2013) Lec 26. Organic Chemistry -- Electrophilic Aromatic Substitution -- Part 3 View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Organic Chemistry (Chem 51B) is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html Recorded on March 15, 2013 Index of Topics: 00:10- Removing Toxic Chemicals with POPs 00:43- Molecular Structures of POPs 04:02- Summary of EAS Substituent Effects: Know This Summary 07:41- 18.9: Over-Activated Anilines and Phenols 11:56- 18.11: EAS on Disubstituted Benzene Rings 15:58- 18.11: EAS on Disubsituted Benzene Rings-no substitution between meta-substituents 18:26- 18.13: Benzylic Bromination 21:48- 18.13: Benzylic Bromination- chalk board 25:11- 18.14B: Reduction of Acyl Side Chains 30:40- 18.14B: Reduction of Acyl Side Chains, example 2 33:52- 18.14C: Reduction of NO2 to NH2 39:28- 18.15: Mulit-step Synthesis Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 7

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 07. Organic Chemistry -- Conversion of Alcohols to Alkyl Halides View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 21, 2015 Index of Topics: 00:11 - Elimination Reactions of Alcohols: Dehydration 08:02 - Carbocation Rearrangement 24:12 - Conversion of Alcohols to Alkyl Halides with H-X Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Chemistry 51B: Organic Chemistry. Lecture 8

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UCI Chem 51B: Organic Chemistry (Winter 2015) Lec 08. Organic Chemistry -- Methods for Converting Alcohols to Alkyl Halides View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html Instructor: Susan King, Ph.D. License: Creative Commons CC-BY-SA Terms of Use: http://ocw.uci.edu/info More courses at http://ocw.uci.edu Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51B) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Recorded January 23, 2015 Index of Topics: 00:49 - Secondary and Tertiary Alkyl Halides 03:33 - Other Methods for Converting Alcohols into Alkyl Halides 31:28 - Converting Alcohols into Sulfonate Esters Required attribution: King, Susan.Chem 51B (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).

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Organic Chemistry 51A. Lecture 06. Acid Strength and Equilibria.

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UCI Chem 51A Organic Chemistry (Fall 2009) Lec 06. Organic Chemistry -- Acid Strength and Equilibria View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html Instructor: James Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw.uci.edu/info. More courses at http://ocw.uci.edu Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/collections/open_chemistry.html This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor James Nowick. Recorded October 7, 2009. Index of Topics: -1:13 Strong Acids -4:16 Weak Acids -8:08 Very Weak Acids -14:32 Position of Acid-Base Equilibria -15:38 Acid-Base Examples -24:34 Trends in pKa -30:42 Resonance Stabilization of Conjugate Bases -34:03 Inductive Stabilization of Conjugate Bases -37:18 S Character and Acid Strength -41:02 Equilibrium Constant of Acid-Base Equilibrium Required attribution: Nowick, James Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).

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